Asymmetric epoxidation of non-functionalized alkenes using transition metal complexes

被引：7

作者：

Abdi, SHR ^{[1
]}

Kureshy, RI ^{[1
]}

Khan, NH ^{[1
]}

Jasra, RV ^{[1
]}

机构：

[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India

来源：

CATALYSIS SURVEYS FROM ASIA | 2004年 / 8卷 / 03期

关键词：

asymmetric catalysis; chiral; non-functionalized alkenes; transition metals; salen; epoxide;

D O I：

10.1023/B:CATS.0000038537.27684.b4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Asymmetric catalytic epoxidation of alkenes such as styrenes, chromenes and indene using transition metal complexes both inhomogeneous and heterogeneous phase has been discussed in this review. The various strategies to make the catalysts recyclable by introducing in-built phase transfer ability, converting these to dimeric form, exchanging into clays and supporting on polymeric or inorganic supports are discussed at length.

引用

页码：187 / 197

页数：11

共 50 条

[1] Asymmetric Epoxidation of Non-Functionalized Alkenes Using Transition Metal Complexes
S.H.R. Abdi
R.I. Kureshy
N.H. Khan
R.V. Jasra
Catalysis Surveys from Asia, 2004, 8 : 187 - 197
[2] Enantio selective epoxidation of non-functionalized alkenes using carbohydrate based salen-Mn(III) complexes
Zhao, Shanshan
Zhao, Jiquan
Zhao, Dongmin
CARBOHYDRATE RESEARCH, 2007, 342 (02) : 254 - 258
[3] Encapsulation of a chiral MnIII(salen) complex in ordered mesoporous silicas:: an approach towards heterogenizing asymmetric epoxidation catalysts for non-functionalized alkenes
Kureshy, RI
Ahmad, I
Khan, NH
Abdi, SHR
Pathak, K
Jasra, RV
TETRAHEDRON-ASYMMETRY, 2005, 16 (21) : 3562 - 3569
[4] Asymmetric epoxidation of alkenes catalyzed by novel chiral porphyrin metal complexes
Sakthipriya, Pachiannan
Ananthi, Nallamuthu
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2016, 20 (06) : 730 - 737
[5] Self-assembled Solvent-regulated Phase Transfer Catalyst for Epoxidation of Non-functionalized Alkenes
Rong Tan
Donghong Yin
Ningya Yu
Yan Ding
Haihong Zhao
Dulin Yin
Catalysis Letters, 2009, 129 : 471 - 477
[6] Self-assembled Solvent-regulated Phase Transfer Catalyst for Epoxidation of Non-functionalized Alkenes
Tan, Rong
Yin, Donghong
Yu, Ningya
Ding, Yan
Zhao, Haihong
Yin, Dulin
CATALYSIS LETTERS, 2009, 129 (3-4) : 471 - 477
[7] Chiral macrocyclic salen Mn(III) complexes catalyzed enantioselective epoxidation of non-functionalized alkenes using NaOCl and urea H2O2 as oxidants
Maity, Nabin Ch.
Abdi, Sayed H. R.
Kureshy, Rukhsana I.
Khan, Noor-ul H.
Suresh, E.
Dangi, Ganga P.
Bajaj, Hari C.
JOURNAL OF CATALYSIS, 2011, 277 (01) : 123 - 127
[8] Organic carbonates as solvents in macrocyclic Mn(III) salen catalyzed asymmetric epoxidation of non-functionalized olefins
Maity, Nabin Ch
Rao, Ganga V. S.
Prathap, K. J.
Abdi, Sayed H. R.
Kureshy, Rukhsana I.
Khan, Noor-ul H.
Bajaj, Hari C.
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 366 : 380 - 389
[9] Aerobic, enantioselective epoxidation of non-functionalized olefins catalyzed by Ni(II) chiral Schiff base complexes
Kureshy, RI
Khan, NH
Abdi, SHR
Iyer, P
Bhatt, AK
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 130 (1-2) : 41 - 50
[10] Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes
Liao, Saihu
List, Benjamin
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (03) : 628 - 631

← 1 2 3 4 5 →