2-Methyl-2-propanol as solvent for o-iodoxybenzoic acid (IBX) oxidation of 1° alcohols to aldehydes

被引：14
|
作者：
Van Arman, Scott A. [1 ]
机构：
[1] Franklin & Marshall Coll, Dept Chem, Lancaster, PA 17604 USA
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 33期
关键词：
SELECTIVE OXIDATION; IODINE(V) REAGENTS; SECONDARY ALCOHOLS; MILD OXIDATION; IONIC LIQUID; CHEMISTRY; N-(2-IODYLPHENYL)ACYLAMIDES; REACTIVITY; 1,2-DIOLS; AMIDES;
D O I：
10.1016/j.tetlet.2009.06.045
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
2-Methyl-2-propanol has been demonstrated to be an effective solvent for IBX oxidation of 1 degrees alcohols to the corresponding aldehydes. IBX has a measurable, but low, solubility in 2-methyl-2-propanol and thus partially avoids the drawbacks inherent in the solubility problems associated with IBX without resorting to less desirable solvents. This may be particularly useful where solubility of the alcohol is also at issue. (C) 2009 Elsevier Ltd. All rights reserved.
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页码：4693 / 4695
页数：3
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