Synchrotron Radiation Study of Interconfigurational 5d-4f Luminescence of Pr3+ in KLuP2O7

被引：7
|
作者：
Trevisani, Mattia [1 ,2 ]
Ivanovskikh, Konstantin [3 ]
Piccinelli, Fabio [1 ,2 ]
Bettinelli, Marco [1 ,2 ]
机构：
[1] Univ Verona, Dept Biotechnol, Lab Luminescent Mat, I-37134 Verona, Italy
[2] UdR Verona, INSTM, I-37134 Verona, Italy
[3] Ural Fed Univ, Inst Phys & Technol, Ekaterinburg 62002, Russia
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2014年 / 69卷 / 02期
关键词：
Pr3+; 5d-4f Luminescence; KLuP2O7; VUV Spectroscopy; Synchrotron Radiation; Scintillator; RARE-EARTH DIPHOSPHATES; DOUBLE PHOSPHATES; RE; LANTHANIDES; NA; LU; CS; RB;
D O I：
10.5560/ZNB.2014-3260
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The double phosphate KLuP2O7 doped with Pr3+ ions was prepared by solid-state reaction. The material obtained was characterized by powder X-ray diffraction. The luminescence spectroscopy and the excited state dynamics of this material were studied upon excitation with VUV synchrotron radiation. The 5d-4f emission of Pr3+ upon both direct and band gap excitation was detected and assigned. The decay kinetics of the Pr3+ 5d-4f emission is characterized by a decay time of about 20 ns and is nearly temperature independent within the range 8-300 K. Both dynamics and energy transfer peculiarities revealed in the study suggested good potentials for application of KLuP2O7:Pr3+ as a fast scintillator material.
引用
收藏
页码：205 / 209
页数：5
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