Endo-selective asymmetric inverse electron-demand 1,3-dipolar cycloaddition reaction of nitrones

被引:0
|
作者
Ashizawa, Tomoko [1 ]
Ohtsuki, Natsuki [1 ]
Miura, Tomoyuki [1 ]
Ohya, Makoto [1 ]
Shinozaki, Takaomi [1 ]
Ikeno, Taketo [1 ]
Yamada, Tohru [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
关键词
cobalt; enantioselectivity; Lewis acid; catalyst; isoxazolidine;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In the presence of a catalytic amount of the optically active cobalt(III) hexafluoroantimonate, the inverse electron-demand 1,3-dipolar cycloaddition reaction of dihydrofuran with nitrones bearing an electron-withdrawing group effectively proceeded to afford the corresponding adducts with excellent endo-selectivity.
引用
收藏
页码:1801 / 1810
页数:10
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