Comparison of Structural Properties of Copper Deposits from Sulfate and Pyrophosphate Electrolytes

被引：3
|
作者：
Arslan, B. [1 ]
Ulgudur, N. [2 ]
Erdogan, M. [3 ]
Imamoglu, I. [2 ]
Karakaya, I. [1 ]
机构：
[1] Middle E Tech Univ, Dept Metall & Mater Eng, TR-06531 Ankara, Turkey
[2] Middle Tech Univ, Dept Environm Eng, Ankara, Turkey
[3] Yildirim Beyazit Univ, Dept Mat Engn, Ankara, Turkey
来源：
FUNDAMENTALS OF ELECTROCHEMICAL GROWTH - FROM UPD TO MICROSTRUCTURES 3 | 2014年 / 58卷 / 32期
关键词：
ELECTRODEPOSITION; BATH;
D O I：
10.1149/05832.0105ecst
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Aluminum is quite often plated to combine the advantages of the light metal with modified surface properties. In this study, copper strike electrodeposits obtained from cyanide and pyrophosphate strike baths were compared in terms of microstructure, and copper pyrophosphate strike was found to yield smoother deposits. Furthermore, about 50 m thick copper depositions on the strike plated aluminum surface, were prepared from acid copper sulfate and copper pyrophosphate electrolytes to compare structural properties of the deposits. Comparison and characterization of copper electrodeposits from copper sulfate and pyrophosphate electrolytes were performed by potentiometry, SEM, roughness, and XRD analyses. Smoother and finer grained copper deposits were obtained from pyrophosphate electrolyte especially at low current densities.
引用
收藏
页码：105 / 113
页数：9
相关论文
共 50 条
  • [41] Wear resistance of copper EDM tool electrode electroformed from copper sulfate baths and pyrophosphate baths
    Ming, Ping Mei
    Zhu, Di
    Bin Zeng, Yong
    Hu, Yang Yang
    INTERNATIONAL JOURNAL OF ADVANCED MANUFACTURING TECHNOLOGY, 2010, 50 (5-8): : 635 - 641
  • [42] Wear resistance of copper EDM tool electrode electroformed from copper sulfate baths and pyrophosphate baths
    Ping Mei Ming
    Di Zhu
    Yong Bin Zeng
    Yang Yang Hu
    The International Journal of Advanced Manufacturing Technology, 2010, 50 : 635 - 641
  • [43] Electrodeposition of copper–zinc alloys in pyrophosphate-based electrolytes
    L.F. Senna
    S.L. Díaz
    L. Sathler
    Journal of Applied Electrochemistry, 2003, 33 : 1155 - 1161
  • [44] THE PROPERTIES OF COPPER CYANIDE ELECTROLYTES - A COMPARISON OF SODIUM AND POTASSIUM FORMULATIONS
    HATHERLEY, PG
    WATKINS, KG
    MCMAHON, M
    TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING, 1992, 70 : 177 - 183
  • [45] Comparison of the corrosion properties of bulk copper samples and an electrodeposited copper nanowire array in a pyrophosphate electrolyte
    Myrzak V.A.
    Surface Engineering and Applied Electrochemistry, 2013, 49 (06) : 457 - 461
  • [46] ELECTRON MICROSCOPE STUDIES ON COPPER DEPOSITS FROM SULFATE AND CYANIDE BATHS
    OKADA, S
    MAGARI, S
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1955, 102 (10) : 580 - 585
  • [47] ADSORPTION OF DIMETHYLOL THIOUREA ON COPPER IN SULFATE ELECTROLYTES
    ANTROPOV, LI
    SRIBNYI, LE
    SOROKIN, VI
    UKRAINSKII KHIMICHESKII ZHURNAL, 1975, 41 (09): : 985 - 986
  • [48] COMPARISON OF THE TENSILE PROPERTIES OF ELECTRODEPOSITS FROM VARIOUS ACID COPPER-SULFATE BATHS
    HAAK, R
    OGDEN, C
    TENCH, D
    PLATING AND SURFACE FINISHING, 1981, 68 (10): : 59 - 62
  • [49] ELECTROCHEMICAL DISSOLUTION OF COPPER IRON SULFIDES IN SULFATE AND SULFATE CHLORIDE ELECTROLYTES
    SABAURI, GN
    SUBBOTINA, EA
    REZNICHENKO, VA
    BRYUKVIN, VA
    PROTECTION OF METALS, 1987, 23 (03): : 339 - 342
  • [50] CEMENTATION OF COPPER FROM ACIDIC SULFATE ELECTROLYTES ON NICKEL-PLATED STEEL
    POPOV, BN
    WHITE, RE
    IVSHIN, JV
    PLATING AND SURFACE FINISHING, 1991, 78 (12): : 61 - 65
12345