Simple and efficient industrial preparation of various trifluoromethyl ketones and derivatives

被引:2
|
作者
Michel, D [1 ]
机构
[1] LONZA Ltd, Valais Works, CH-3930 Visp, Switzerland
关键词
building blocks; ethyl 4,4,4-trifluoroacetoacetate; fluorinated yruvaldehydes; trifluoromethyl ketones;
D O I
10.2533/000942904777678208
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trifluoromethyl ketones are important tools in organic synthesis, useful especially for the production of complex fluorinated compounds. The preparation of ethyl 4,4,4-trifluoroacetoacetate and several attractive applications are described, as well as a new route leading to different fluorinated pyruvalclehydes and some examples of applications.
引用
收藏
页码:100 / 103
页数:4
相关论文
共 50 条
  • [21] SHORT AND EFFICIENT PREPARATION OF TRIFLUOROMETHYL VINYL SULFIDES
    BEGUE, JP
    BONNETDELPON, D
    MBIDA, A
    TETRAHEDRON LETTERS, 1993, 34 (48) : 7753 - 7754
  • [22] EFFICIENT METHODS FOR THE PREPARATION OF ACETYLENIC KETONES
    VERKRUIJSSE, HD
    HEUSKLOOS, YA
    BRANDSMA, L
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 338 (03) : 289 - 294
  • [23] Dicyclic derivatives of simple aliphatic ketones.
    King, FE
    JOURNAL OF THE CHEMICAL SOCIETY, 1935, : 982 - 984
  • [24] EFFICIENT PREPARATION OF PEPTIDYL PENTAFLUOROETHYL KETONES
    ANGELASTRO, MR
    BURKHART, JP
    BEY, P
    PEET, NP
    TETRAHEDRON LETTERS, 1992, 33 (23) : 3265 - 3268
  • [25] A SIMPLE AND EFFICIENT PREPARATION OF 3-ARYL-3-TRIFLUOROMETHYL-3H-DIAZIRINYL SULFOXIDES AND SULFONES
    FINDLAY, JBC
    FISHWICK, CWG
    KERSEY, ID
    WARD, P
    SYNTHESIS-STUTTGART, 1995, (05): : 553 - 556
  • [26] A SIMPLE, NOVEL METHOD FOR THE PREPARATION OF TRIFLUOROMETHYL IODIDE AND DIIODODIFLUOROMETHANE
    SU, DB
    DUAN, JX
    CHEN, QY
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (11) : 807 - 809
  • [27] A Simple and Efficient Preparation of 3-Aryl-3-Trifluoromethyl-3H-Diazirinyl Sulfoxides and Sulfones
    Findlay, J. B. C.
    Fishwick, C. W. G.
    Kersey, I. D.
    Ward, P.
    Synlett, 1995, (05)
  • [28] β-Trifluoromethyl α,β-unsaturated Ketones: Efficient Building Blocks for Diverse Trifluoromethylated Molecules
    Chaudhary, Bharatkumar
    Kulkarni, Neeraj
    Saiyed, Nehanaz
    Chaurasia, Meenakshi
    Desai, Surbhi
    Potkule, Sagar
    Sharma, Satyasheel
    ADVANCED SYNTHESIS & CATALYSIS, 2020, 362 (22) : 4794 - 4819
  • [29] A Novel Efficient Synthesis of Heteroaryl Substituted a, QQ -Unsaturated Trifluoromethyl Ketones
    Nenajdenko, V. G.
    Krasovsky, A. L.
    Lebedev, M. V.
    Balenkova, E. S.
    Synlett, (12):
  • [30] The preparation of simple function anils of aliphatic ketones
    Montagne, M
    Rousseau, G
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1933, 196 : 1165 - 1167