A conjugate Lewis base-Bronsted acid catalyst for the sulfenylation of nitrogen containing heterocycles under mild conditions

被引：59
|
作者：
Nalbandian, Christopher J. [1 ]
Miller, Eric M. [1 ]
Toenjes, Sean T. [1 ]
Gustafson, Jeffery L. [1 ]
机构：
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 09期
关键词：
C-H SULFENYLATION; 3-SULFENYL INDOLES; RICH ARENES; CHLORINATION; HETEROARENES;
D O I：
10.1039/c6cc09998j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalysts that contain a thiourea tethered to a carboxylic acid were found to affect the sulfenylation of indoles and other N-heterocycles on the hour time scale at room temperature. The mild nature of these conditions allowed for the incorporation of diverse functionalities into more complex heterocycles.
引用
收藏
页码：1494 / 1497
页数：4
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