Bis(μ-biphenyl-2,2′-dicarboxylato)bis[(2,2′-bipyridine)copper(II)]

被引：2
|
作者：
An, Zhe [1 ]
Cui, Rui-Hai [2 ]
Zhou, Ru-Jin [1 ]
机构：
[1] Maoming Univ, Sch Chem & Life Sci, Maoming 525000, Peoples R China
[2] Harbin Univ, Sch Chem & Life Sci, Harbin 150080, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809008976
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C14H8O4)(2)(C10H8N2)(2)], was obtained by solvothermal synthesis. The Cu-II atom is coordinated by one chelating 2,2'-bipyridine ligand and two carboxyl groups from different biphenyl-2,2'-dicarboxylate ligands, leading to a distorted octahedral environment. Each carboxylate group makes one short Cu-O bond [1.9608 (14) and 1.9701 (14) angstrom] and one longer Cu-O contact [2.4338 (17) and 2.5541 (17) angstrom] to each Cu-II atom. The biphenyl-2,2'-dicarboxylate ligands bridge between Cu-II atoms, forming a dinuclear complex around a crystallographic inversion centre.
引用
收藏
页码：M412 / U631
页数：9
相关论文
共 50 条
  • [21] Bis(2,2′-bipyridine)(2-hydroxy-2,2-diphenylacetato)copper(II) nitrate dihydrate
    Wang, Xiao-Jun
    Zheng, Chun
    Mai, Shao-Wei
    Xu, Xuan
    Luo, Yi-Fan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1245 - U717
  • [22] 2,2'-BIS(ACETAMIDO)BIPHENYL
    REBOUL, JP
    PEPE, G
    SIRI, D
    ODDON, Y
    CARANONI, C
    RAHAL, H
    SOYFER, JC
    BARBE, J
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 735 - 738
  • [23] 2,2′-(biphenyl-2,2′-diyldioxy)diacetohydrazide
    Ibad, Farooq
    Mustafa, Asra
    Shah, Muhammad Raza
    VanDerveer, Donald
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1130 - U2639
  • [24] N,N′-(Biphenyl-2,2′-diyl)bis(furan-2-carboxamide)
    Kee, Chin Hui
    Thomas, Noel F.
    Ariffin, Azhar
    Awang, Khalijah
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : 01556 - U2305
  • [25] Pentaaqua-1K2O,2K3O-bis(2,2′-bipyridine)-1K2N,N′;2K2N,N′-μ-biphenyl-2,2′-dicarboxylato-1:2K2O:O′-biphenyl-2,2′-dicarboxylato-1KO-dimanganese(II) tetrahydrate
    Du, Lin
    Fang, Rui-Bing
    Zhao, Qi-Hua
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M1439 - M1441
  • [26] Bis(μ-2-carboxylatoethylphosphonato)bis[aqua(2,2′-bipyridine)zinc(II)]
    Ying, Shao-Ming
    Li, Xin-Fa
    Chen, Wen-Tong
    Liu, Dong-Sheng
    Liu, Jiu-Hui
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M555 - M557
  • [27] Bis(μ-carboxylatoethylphosphonato)bis-[aqua(2,2′-bipyridine)manganese(II)]
    Ying, Shao-Ming
    Chen, Yun
    Luo, Qiu-Yan
    Xv, Ya-Ping
    Liu, Dong-Sheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M166 - U1572
  • [28] Polymeric bis[bis(2,2′-bipyridine)nickel(II)] hexavanadate(V)
    Lin, BZ
    Liu, SX
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 : 243 - 245
  • [29] THIOETHER, THIOLATO, AND 1,1-DITHIOATO COMPLEXES OF BIS(2,2'-BIPYRIDINE)RUTHENIUM(II) AND BIS(2,2'-BIPYRIDINE)OSMIUM(II)
    ROOT, MJ
    SULLIVAN, BP
    MEYER, TJ
    DEUTSCH, E
    INORGANIC CHEMISTRY, 1985, 24 (18) : 2731 - 2739
  • [30] catena-Poly[[diaqua(2,2′-bipyridine-κ2N,N′)nickel(II)]-μ-biphenyl-2,2′-dicarboxylato-κ2O:O′]
    An, Zhe
    Niu, Xian-Chun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1547 - U634
12345