Palladium-Catalyzed Chelation-Assisted C-H Bond Halogenation: Selective Chlorination of 2-Arylpyridines with Acid Chlorides

被引：13
|
作者：
Jafarpour, Farnaz [1 ]
Hazrati, Hamideh [1 ]
Zarei, Samaneh [1 ]
Izadidana, Sara [1 ]
机构：
[1] Univ Tehran, Sch Chem, Coll Sci, Tehran 141556455, Iran
来源：
SYNTHESIS-STUTTGART | 2014年 / 46卷 / 09期
基金：
美国国家科学基金会;
关键词：
aroyl chlorides; C-H activation; chlorination; palladium; 2-phenylpyridine; ORTHO-BROMINATION; COUPLING REACTIONS; DIRECTING-GROUP; ARYL CHLORIDES; FUNCTIONALIZATION; IODINATION; HALIDES; ARENES; ARYLATION; COORDINATION;
D O I：
10.1055/s-0033-1340869
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed chelation-assisted C-H bond halogenation of arenes using acid chlorides as chlorinating agents is reported. This method provides a monoselective, straightforward, and clean route for the construction of aryl chlorides as privileged motifs in organic transformations.
引用
收藏
页码：1224 / 1228
页数：5
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