Low-temperature methanol synthesis (LTMS) in liquid phase on novel copper-based catalysts

被引:24
|
作者
Chu, W
Zhang, T
He, CH
Wu, YT
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Sichuan 610041, Peoples R China
[2] Sichuan Univ, Dept Chem Engn, Chengdu 610065, Peoples R China
[3] Chinese Acad Sci, Dalian Inst Chem Phys, Liaoning 116023, Peoples R China
基金
中国国家自然科学基金;
关键词
methanol synthesis; low temperature; LTMS; catalyst; Cu-Cr-Al; co-precipitation from sol state; slurry; TPD characterization;
D O I
10.1023/A:1015384015528
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel Cu-Cr based catalysts with alumina promotion have been prepared and studied in low-temperature methanol synthesis (LTMS) in a slurry reactor. The new method of co-precipitation from the sol state gave better results than those of three other preparation methods. From the results of temperature programmed desorption and XRD, there were more active sites in the presence of alumina.
引用
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页码:129 / 132
页数:4
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