The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

被引：80
|
作者：
Kakiuchi, F [1 ]
Sonoda, M [1 ]
Tsujimoto, T [1 ]
Chatani, N [1 ]
Murai, S [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 10期
关键词：
D O I：
10.1246/cl.1999.1083
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(K)(2)(CO)(PPh3)(3)-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via pi-bonded mode.
引用
收藏
页码：1083 / 1084
页数：2
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