2-Hydroxybenzophenone UV-absorbers containing 2,2,6,6-tetramethylpiperidine (HALS) group - benzoylation of corresponding phenol derivatives

被引:19
|
作者
Zakrzewski, J
Szymanowski, J
机构
[1] Inst Ind Organ Chem, PL-03236 Warsaw, Poland
[2] Poznan Univ Technol, Inst Chem Technol & Engn, PL-60965 Poznan, Poland
关键词
2-hydroxybenzophenone UV-absorbers; 2,2,6,6-tetramethylpiperidine light stabilizers; HALS; nitroxyl radicals; benzoylation; benzotrichloride;
D O I
10.1016/S0141-3910(99)00126-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Phenol derivatives containing 2,2,6,6-tetramethylpiperidine group were successfully benzoylated with both benzoyl chloride in the presence of aluminium chloride and benzotrichloride in aqueous sodium hydroxide solution. The 2-hydroxybenzophenone UV-absorbers bearing light stabilizing fragment - 2,2,6,6-tetramethylpiperidine nucleus - were synthesized in this way. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:279 / 283
页数:5
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