Thermodynamics of dissolution of some dicarboxylic acids in water/ethane-1,2-diol mixtures

被引：4
|
作者：
El-Naggar, GA [1 ]
Selim, SM
Zaghloul, AA
Amira, MF
机构：
[1] Univ Alexandria, Fac Educ, Dept Chem, Damanhour Branch, Alexandria, Egypt
[2] Univ Alexandria, Fac Sci, Dept Chem, Alexandria, Egypt
来源：
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2002年 / 216卷 / 10期
关键词：
dicarboxylic acids; solvent effects; dissociation constant; thermodynamics; relative permittivity;
D O I：
10.1524/zpch.2002.216.10.1239
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The pK(1) and pK(2) values of malic, malonic, maleic, succinic, tartaric, and phthalic acids have been determined in ethane-1,2-diol-water media of varying solvent compositions (0-50 wt% ethane-1,2-diol) within the temperature range (25-65 degreesC). An extrathermodynamic analysis of the obtained results have been examined, in the light of DeltaHdegrees-DeltaSdegrees relationship. The pK values have been correlated with the relative permittivity of the medium according to Born's electrostatic model.
引用
收藏
页码：1239 / 1260
页数：22
相关论文
共 50 条
  • [21] Dielectric properties in ternary mixtures of ethane-1,2-diol+1,2-dimethoxyethane plus water
    Foca, G
    Manfredini, M
    Manzini, D
    Marchetti, A
    Pigani, L
    Sighinolfi, S
    Tassi, L
    Ulrici, A
    INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2004, 25 (03) : 839 - 855
  • [22] meso-1,2-bis(pyridin-2-yl)ethane-1,2-diol
    Bjernemose, JK
    Bond, AD
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O741 - O742
  • [23] RUTHENIUM (VIII) OXIDE CATALYZED OXIDATION OF ETHANE-1,2-DIOL AND PROPANE-1,2-DIOL BY HEXACYANOFERRATE (III) IN AQUEOUS ALKALINE-MEDIUM
    VERMA, MK
    TANDON, PK
    SINGH, MP
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1987, 268 (03): : 565 - 572
  • [24] Physical data relevant to the use of ethane-1,2-diol (ethylene glycol) as a cryoprotectant.
    Hayes, AR
    Pegg, DE
    CRYO-LETTERS, 1996, 17 (04) : 249 - 256
  • [25] THERMODYNAMIC BEHAVIOR OF SOME ELECTROLYTES IN ETHANE-1,2-DIOL FROM-10 TO +80-DEGREES-C
    CORRADINI, F
    MARCHESELLI, L
    TASSI, L
    TOSI, G
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1993, 71 (08): : 1265 - 1272
  • [26] Novozym 435 catalyzed regioselective acylation of ethane-1,2-diol in the presence of ionic liquids
    Tahmina Yasmin
    Tao Jiang
    Buxing Han
    Catalysis Letters, 2007, 116 : 46 - 49
  • [27] Excess volumes of 1,4-dioxane + ethane-1,2-diol at 298.15 K
    Skrane, Wolfgang
    Cibulka, Ivan
    Hnedkovsky, Lubomir
    Journal of Chemical and Engineering Data, 1995, 40 (04):
  • [28] Novozym 435 catalyzed regioselective acylation of ethane-1,2-diol in the presence of ionic liquids
    Yasmin, Tahmina
    Jiang, Tao
    Han, Buxing
    CATALYSIS LETTERS, 2007, 116 (1-2) : 46 - 49
  • [29] SIMPLE ENZYMATIC SCREENING ASSAY FOR ETHYLENE-GLYCOL (ETHANE-1,2-DIOL) IN SERUM
    HANSSON, P
    MASSON, P
    CLINICA CHIMICA ACTA, 1989, 182 (01) : 95 - 102
  • [30] Kinetics and mechanism of chromium(III)-catalysed oxidation of ethane-1,2-diol and propane-1,2-diol by cerium(IV) in aqueous sulfuric acid media
    Das, AK
    Mondal, SK
    Kar, D
    Bhuin, GK
    Roy, A
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2000, 77 (05) : 223 - 227
12345