Total synthesis of malayamycin A and analogues

被引：22

作者：

Hanessian, Stephen ^{[1
]}

Marcotte, Stephane ^{[1
]}

Machaalani, Roger ^{[1
]}

Huang, Guobin ^{[1
]}

Pierron, Julien ^{[1
]}

Loiseleur, Olivier ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Stn Ctr Ville, Montreal, PQ H3C 3J7, Canada

来源：

TETRAHEDRON | 2006年 / 62卷 / 22期

基金：

加拿大自然科学与工程研究理事会;

关键词：

C-nucleoside; thioglycoside; ring closure metathesis; perhydrofuropyran;

D O I：

10.1016/j.tet.2005.12.066

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of the bicyclic C-nucleoside malayamycin A is described starting with D-ribonolactone. A new method was developed to obtain preparatively important quantities of beta-pseudouridine, which was used as an intermediate. The synthesis of a carba N-nucleoside analogue of malayamycin A is also described. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5201 / 5214

页数：14

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