3D metal-organic frameworks incorporating water-soluble tetra-p-sulfonatocalix[4]arene

被引：26

作者：

Liao, Wuping ^{[1
]}

Liu, Ce ^{[1
]}

Wang, Xiaofei ^{[1
]}

Zhu, Guangshan ^{[2
]}

Zhao, Xiaojun ^{[2
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 11期

基金：

中国国家自然科学基金;

关键词：

MOLECULAR CAPSULES; CROWN-ETHERS; COORDINATION; COMPLEXES; CONFINEMENT; ADSORPTION; HYDROGEN; BILAYER; SPHERES; DESIGN;

D O I：

10.1039/b908189e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water-soluble tetra-p-sulfonatocalix[4]arene, acting as a four-connected node, bridges the rare earth cations into a 3D porous MOF in which 1D smaller circular hydrophilic channels and larger quadratic ones are lined up along the c axis and interconnected to each other by the calixarene cavities and other interstices.

引用

页码：2282 / 2284

页数：3

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