Synthesis and transition metal coordination of 2-(azidomethyl) phenyl isocyanide

被引：11
|
作者：
Facchin, G
Michelin, RA
Mozzon, M
Pugliese, S
Sgarbossa, P
Tassan, A
机构：
[1] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy
[2] CNR, Dipartimento Proc Chim Ingn, ISTM, I-35131 Padua, Italy
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 11期
关键词：
isocyanide; functionalized isocyanide; azido; transition metal complexes;
D O I：
10.1016/S1387-7003(02)00598-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 2-(chloromethyl)phenyl formamide, 2-(CH2Cl)C6H4NHCHO, with NaN3 in DMSO at room temperature affords 2-(azidomethyl)phenyl formamide, 2-(CH2N3)C6H4NHCHO (1), which is then dehydrated to 2-(azidomethyl)phenyl isocyanide, 2-(CH2N3)C(6)H(4)Nequivalent toC, (2) upon reaction with SOCl2 in DMF at low temperature. The coordination ability of the isocyanide 2 has been tested towards some Pt(II), Pd(II) and W(0) metal complexes to yield derivatives of the type [PtCl2(CNC6H4-2-CH2N3)(2)], [PdCl2(CNC6H4-2-CH2N3)(PPh3)] and [W(CO)(5)(CNC6H4-2-CH2N3)], respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：915 / 918
页数：4
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