NaMn6(P2O7)2(P3O10) and KCd6(P2O7)2(P3O10)

被引：9
|
作者：
Bennazha, J
El-Maadi, A
Boukhari, A
Holt, EM [1 ]
机构：
[1] Oklahoma State Univ, Dept Chem, Stillwater, OK 74078 USA
[2] Univ Mohammed 5, Lab Associe Francophone 501, Lab Chim Solide Appl, Rabat, Morocco
[3] Univ Hassan 2, Fac Sci & Tech, Dept Chim, Mohammadia, Morocco
[4] Univ Ibn Tofail, Fac Sci Kenitra, Dept Chim, Lab Physicochim Mat, Kenitra, Morocco
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 06期
关键词：
D O I：
10.1107/S0108270102006753
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structures of two new diphosphates, sodium hexamanganese bis(diphosphate) triphosphate, NaMn6(P2O7)2 (P3O10), and potassium hexacadmium bis(diphosphate) triphosphate, KCd6(P2O7)2 (P3O10), confirm the rigidity of the M6(P2O7)2 (P3O10) matrix (M is Mn or Cd) and the relatively fixed dimensions of the tunnels extending in the a direction of the unit cell. The compounds are isomorphous; the P2O74- anion and the alkali metal cations lie on mirror planes. Bond-valence analysis of the bonding details of the atoms found within the tunnels permits a prediction of the conductivity.
引用
收藏
页码：I76 / I78
页数：3
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