Carbon Dioxide Sensitivity of Zeolitic Imidazolate Frameworks

被引：74

作者：

Mottillo, Cristina ^{[1
,2
]}

Friscic, Tomislav ^{[1
,2
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada

[2] McGill Univ, FRQNT Ctr Green Chem & Catalysis, Montreal, PQ H3A 0B8, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2014年 / 53卷 / 29期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

carbon dioxide; carbon sequestration; metal-organic frameworks; solvent-free reactions; zeolitic imidazolate frameworks; METAL-ORGANIC FRAMEWORKS; RAY SINGLE-CRYSTAL; COORDINATION POLYMERS; AZOLATE FRAMEWORKS; THERMAL-STABILITY; CO2; ADSORPTION; PORE-SIZE; ZIF-8; MEMBRANES; POLYMORPHISM;

D O I：

10.1002/anie.201402082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zeolitic imidazolate frameworks of zinc, cobalt, and cadmium, including the framework ZIF-8 commercially sold as Basolite Z1200, exhibit surprising sensitivity to carbon dioxide under mild conditions. The frameworks chemically react with CO2 in the presence of moisture or liquid water to form carbonates. This effect, which has been previously not reported in metal-organic framework chemistry, provides an explanation for conflicting reports on ZIF-8 stability to water and is of outstanding significance for evaluating the potential applications of metal-organic frameworks, especially for CO2 sequestration.

引用

页码：7471 / 7474

页数：4

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