The Inorganic-Organic Hybrid Compound {[Mn(trien)]2SnS4}•4H2O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS4]4- Tetrahedron

被引：44
|
作者：
Pienack, Nicole [1 ]
Naether, Christian [1 ]
Bensch, Wolfgang [1 ]
机构：
[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 12期
关键词：
Tin; Sulfur; Structure elucidation; Organic-inorganic hybrid composites; Coordination modes; TIN SULFIDE MATERIALS; CRYSTAL-STRUCTURES; SOLVOTHERMAL SYNTHESIS; SPECTROSCOPIC PROPERTIES; THIOSTANNATES; TRANSITION; COMPLEXES; IONS;
D O I：
10.1002/ejic.200801093
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound {[Mn(C6H18N4)](2)SnS4}center dot 4H(2)O (C6H18N4 = triethylenetetramine) was obtained under solvothermal conditions. In the structure of the {[Mn(C6H18N4)](2)SnS4}(infinity), chain, two S atoms of the [SnS4](4)(-) anion act. in a hitherto never observed mu(3) bridging mode that connects the Mn2S2N8 di-octahedra. The Mn2+ ions are octahedrally coordinated by four N and two S atoms, and two symmetry-related octahedra share a common S-S edge. Three of the H2O molecules are joined into chains through H-bonding interactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：1575 / 1577
页数：3
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