The Inorganic-Organic Hybrid Compound {[Mn(trien)]2SnS4}•4H2O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS4]4- Tetrahedron

被引：44
|
作者：
Pienack, Nicole [1 ]
Naether, Christian [1 ]
Bensch, Wolfgang [1 ]
机构：
[1] Univ Kiel, Inst Inorgan Chem, D-24118 Kiel, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 12期
关键词：
Tin; Sulfur; Structure elucidation; Organic-inorganic hybrid composites; Coordination modes; TIN SULFIDE MATERIALS; CRYSTAL-STRUCTURES; SOLVOTHERMAL SYNTHESIS; SPECTROSCOPIC PROPERTIES; THIOSTANNATES; TRANSITION; COMPLEXES; IONS;
D O I：
10.1002/ejic.200801093
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound {[Mn(C6H18N4)](2)SnS4}center dot 4H(2)O (C6H18N4 = triethylenetetramine) was obtained under solvothermal conditions. In the structure of the {[Mn(C6H18N4)](2)SnS4}(infinity), chain, two S atoms of the [SnS4](4)(-) anion act. in a hitherto never observed mu(3) bridging mode that connects the Mn2S2N8 di-octahedra. The Mn2+ ions are octahedrally coordinated by four N and two S atoms, and two symmetry-related octahedra share a common S-S edge. Three of the H2O molecules are joined into chains through H-bonding interactions. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：1575 / 1577
页数：3
相关论文
共 50 条
  • [1] Stabilization of (SnS4)4- anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(IV) {[Mn(phen)]2(SnS4)}n•nH2O exhibiting an unprecedented link mode of the (SnS4)4- anion
    Liu, Guang-Ning
    Guo, Guo-Cong
    Chen, Feng
    Guo, Sheng-Ping
    Jiang, Xiao-Ming
    Yang, Chen
    Wang, Ming-Sheng
    Wu, Mei-Feng
    Huang, Jin-Shun
    CRYSTENGCOMM, 2010, 12 (12): : 4035 - 4037
  • [2] Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} • 4H2O
    Wang, K.
    Li, J.
    Liang, Z. J.
    Ma, P. T.
    Zhang, D. D.
    Niu, J. Y.
    Wang, J. P.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (11) : 795 - 799
  • [3] Divanadate-based inorganic-organic hybrid compound: {[Cu(En)2]2V2O7} · 4H2O
    K. Wang
    J. Li
    Z. J. Liang
    P. T. Ma
    D. D. Zhang
    J. Y. Niu
    J. P. Wang
    Russian Journal of Coordination Chemistry, 2017, 43 : 795 - 799
  • [4] Redetermination of the crystal structure of [Na4(H2O)14]SnS4: a compound containing a novel chain of aquated sodium ions
    Roger D. Willett
    Ashwani Vij
    Joseph M. Imhof
    David A. Cleary
    Journal of Chemical Crystallography, 2000, 30 : 405 - 410
  • [5] Redetermination of the crystal structure of [Na4(H2O)14]SnS4:: a compound containing a novel chain of aquated sodium ions
    Willett, RD
    Vij, A
    Imhof, JM
    Cleary, DA
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (06) : 405 - 410
  • [6] Hydrothermal synthesis and crystal structure of inorganic-organic hybrid compound [H3NC2H4NH2]VOPO4
    Zhang, D
    Shi, Z
    Feng, SH
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2001, 17 (03) : 249 - 252
  • [7] Hydrothermal Synthesis and Crystal Structure of Inorganic-organic Hybrid Compound [H3NC2H4NH2]VOPO4
    ZHANG Dong
    Chemical Research in Chinese Universities, 2001, (03) : 249 - 252
  • [8] First-principles study of organic-inorganic hybrid framework compound Mn(C4H4O4)
    Kanungo, Sudipta
    Saha-Dasgupta, T.
    PHYSICAL REVIEW B, 2011, 84 (13)
  • [9] Synthesis and characterization of an organic-inorganic hybrid crystal: 2[Co(en)3](V4O13)•4H2O
    Vosegaard, Emilie Skytte
    Mamakhel, Mohammad Aref Hasen
    Parmar, Vijay Singh
    Bertelsen, Andreas Dueholm
    Iversen, Bo Brummerstedt
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2024, 80 : 488 - 494
  • [10] Thermal transformations of Mn5H2(PO4)4•4H2O crystals
    Galkova, TN
    Samuskevich, VV
    ZHURNAL NEORGANICHESKOI KHIMII, 1998, 43 (08): : 1264 - 1269
12345