3-hydroxy-6-[(4-hydroxyphenylamino)methylene]cyclohexa-2,4-dienone and 2-hydroxy-6-[(4-hydroxyphenylamino)-methylene]cyclohexa-2,4-dienone

被引:20
|
作者
Kosar, B [1 ]
Büyükgüngör, O
Albayrak, C
Odabasoglu, M
机构
[1] Ondokuz Mayis Univ, Dept Phys, TR-55139 Samsun, Turkey
[2] Ondokuz Mayis Univ, Dept Chem, TR-55139 Samsun, Turkey
关键词
D O I
10.1107/S0108270104010832
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compounds, both C13H11NO3, exist as the keto-amine tautomers, and the formal hydroxyl H atoms, which display strong intramolecular hydrogen bonds, are located on the N atoms. This is a verification of the preference for the keto-amine tautomeric form in the solid state. The 2-hydroxy isomer has two independent molecules, with the molecules linked by intramolecular N-H...O and O-H...O and intermolecular O-H...O hydrogen bonds into three-dimensional networks.
引用
收藏
页码:O458 / O460
页数:3
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