Pd-catalyzed ligand-free Suzuki reaction of β-substituted allylic halides with arylboronic acids in water

被引：15

作者：

Dong, Chaonan ^{[1
]}

Zhang, Lingjuan ^{[1
]}

Xue, Xiao ^{[1
]}

Li, Huanrong ^{[1
]}

Yu, Zhiyong ^{[1
]}

Tang, Weijun ^{[1
]}

Xu, Lijin ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 22期

基金：

中国国家自然科学基金;

关键词：

CROSS-COUPLING REACTIONS; BAYLIS-HILLMAN ADDUCTS; AQUEOUS-MEDIA; ARYL HALIDES; PALLADIUM CATALYSTS; MIYAURA COUPLINGS; BORONIC ACIDS; SUPPORTED PALLADIUM; REUSABLE CATALYST; HIGHLY EFFICIENT;

D O I：

10.1039/c3ra47813k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalyst system consisting of Pd(TFA)(2) and KOH allows for a wide range of beta-substituted allylic halides to react efficiently with various arylboronic acids in neat water under ligand-free conditions, affording the allylated arenes in high yields with broad functional group tolerance and up to 7.4 x 10(5) TON and 15 416 h(-1) TOF.

引用

页码：11152 / 11158

页数：7

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