Catalytic asymmetric cross-coupling

被引：47

作者：

Hayashi, T ^{[1
]}

机构：

[1] Kyoto Univ, Dept Chem, Fac Sci, Sakyo Ku, Kyoto 6068502, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 653卷 / 1-2期

关键词：

cross-coupling; palladium catalyst; nickel catalyst; allylsilanes; biaryls; carbon-carbon bond formation;

D O I：

10.1016/S0022-328X(02)01272-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Asymmetric cross-coupling of secondary alkylmagnesium and -zinc reagents with aryl and alkenyl halides in the presence of nickel or palladium catalysts coordinated with chiral phosphine ligands give optically active cross-coupling products, This asymmetric cross-coupling is applied to the asymmetric synthesis of chiral allylic silanes (95% ee). Axially chiral biaryls are prepared by asymmetric cross-coupling between two aryl groups (95% ee) or by enantioposition-selective cross-coupling (99% ee). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：41 / 45

页数：5

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