Synthesis of β-alkyl cyclopentanones in high enantiomeric excess via copper-catalyzed asymmetric conjugate reduction

被引:166
|
作者
Moritani, Y [1 ]
Appella, DH [1 ]
Jurkauskas, V [1 ]
Buchwald, SL [1 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
关键词
D O I
10.1021/ja0009525
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:6797 / 6798
页数:2
相关论文
共 50 条
  • [21] Copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones
    Feringa, BL
    Badorrey, R
    Peña, D
    Harutyunyan, SR
    Minnaard, AJ
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (16) : 5834 - 5838
  • [22] Copper-catalyzed asymmetric conjugate addition with Grignard reagents and SimplePhos ligands
    Palais, Laetitia
    Alexakis, Alexandre
    TETRAHEDRON-ASYMMETRY, 2009, 20 (24) : 2866 - 2870
  • [23] Chiral amides via copper-catalyzed enantioselective conjugate addition
    Schoonen, Anne K.
    Fernandez-Ibanez, Maria A.
    Fananas-Mastral, Martin
    Teichert, Johannes F.
    Feringa, Ben L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [24] Asymmetric Copper-Catalyzed Addition of Grignard Reagents to Aryl Alkyl Ketones
    Madduri, Ashoka V. R.
    Harutyunyan, Syuzanna R.
    Minnaard, Adriaan J.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (13) : 3164 - 3167
  • [25] Asymmetric Synthesis of γ-Amino Alcohols by Copper-Catalyzed Hydroamination
    Ichikawa, Saki
    Buchwald, Stephen L.
    ORGANIC LETTERS, 2019, 21 (21) : 8736 - 8739
  • [26] Copper-catalyzed conjugate addition of in situ formed alkyl boranes to α,β-unsaturated ketones
    Mravec, Bernard
    Plevova, Kristina
    Sebesta, Radovan
    MONATSHEFTE FUR CHEMIE, 2019, 150 (02): : 295 - 302
  • [27] Copper-catalyzed conjugate addition of in situ formed alkyl boranes to α,β-unsaturated ketones
    Bernard Mravec
    Kristína Plevová
    Radovan Šebesta
    Monatshefte für Chemie - Chemical Monthly, 2019, 150 : 295 - 302
  • [28] Copper-catalyzed asymmetric reduction of 3,3-diarylacrylonitriles
    Lee, Daehyung
    Yang, Youngmin
    Yun, Jaesook
    ORGANIC LETTERS, 2007, 9 (14) : 2749 - 2751
  • [29] Dynamic kinetic resolution of α,β-unsaturated lactones through asymmetric copper-catalyzed conjugate reduction:: Application to the total synthesis of eupomatilone-3
    Rainka, MP
    Milne, JE
    Buchwald, SL
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) : 6177 - 6180
  • [30] Asymmetric Synthesis of β-Aminoboronates via Copper-Catalyzed Reductive Coupling of Vinyl Boronates with Imines
    He, Jing
    Seo, Cham Bi
    Yoon, Wan Seok
    Yun, Jaesook
    ORGANIC LETTERS, 2023, 25 (29) : 5492 - 5497