PtMo Alloy and MoOx@Pt Core-Shell Nanoparticles as Highly CO-Tolerant Electrocatalysts

被引：159

作者：

Liu, Zhufang ^{[1
]}

Hu, Jenny E. ^{[2
]}

Wang, Qi ^{[3
]}

Gaskell, Karen ^{[1
]}

Frenkel, Anatoly I. ^{[3
]}

Jackson, Gregory S. ^{[3
]}

Eichhorn, Bryan ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

[2] Univ Maryland, Dept Mech Engn, College Pk, MD 20742 USA

[3] Yeshiva Univ, Dept Phys, New York, NY 10016 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 20期

关键词：

CARBON-MONOXIDE; H-2/CO MIXTURES; OXIDATION; ELECTROOXIDATION; PLATINUM;

D O I：

10.1021/ja901303d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

PtMo alloy and MoOx@Pt core-shell nanoparticles (NPs) were successfully synthesized by a chemical coreduction and sequential chemical reduction method, respectively. Both the carbon-supported alloy and core-shell NPs show substantially higher CO tolerance, compared to the commercialized E-TEK PtRu alloy and Pt catalyst. These novel nanocatalysts can be potentially used as highly CO-tolerant anode etectrocatalysts in proton exchange membrane fuel cells.

引用

页码：6924 / +

页数：3

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