Palladium/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination

被引：47
|
作者：
Feng, Bin [1 ,2 ]
Cheng, Hong-Gang [1 ,2 ]
Chen, Jia-Rong [1 ,2 ]
Deng, Qiao-Hui [1 ,2 ]
Lu, Liang-Qiu [1 ,2 ]
Xiao, Wen-Jing [1 ,2 ]
机构：
[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Hubei, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 67期
基金：
美国国家科学基金会;
关键词：
RING-CLOSING METATHESIS; ASYMMETRIC-SYNTHESIS; HYBRID LIGANDS; ALKYLATION; ALCOHOLS; SUBSTITUTION; DERIVATIVES; ALLYLATION; COMPLEX; VERSATILE;
D O I：
10.1039/c4cc03920c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Pd/sulfoxide-phosphine-catalyzed highly enantioselective allylic etherification and amination with a wide range of O- and N-nucleophiles have been developed (up to 97% yield, 985% ee). The products can also be conveniently transformed into biologically active chiral heterocycles.
引用
收藏
页码：9550 / 9553
页数：4
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