Low-temperature melt processing of organic-inorganic hybrid films

被引：50
|
作者：
Mitzi, DB
Medeiros, DR
DeHaven, PW
机构：
[1] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA
[2] IBM Corp, Hopewell Jct, NY 12533 USA
来源：
CHEMISTRY OF MATERIALS | 2002年 / 14卷 / 07期
关键词：
D O I：
10.1021/cm020264f
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The thermal properties of semiconducting tin(II) iodide based hybrid perovskites have been modified by tailoring the organic component of the structure, thereby reducing the melting temperature (b) well below the decomposition point (c) for these systems. The more stable melt phase has enabled the first demonstration of crystallographically oriented, melt-processed, hybrid films on flexible Kapton substrates. In addition, a premelting structural transition (a) has been characterized for the perovskite systems using thermal analysis and temperature-programmed X-ray diffraction.
引用
收藏
页码：2839 / +
页数：4
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