Synthesis of multiwall carbon nanotube wrapped Co(OH)2 flakes: A high-performance supercapacitor

被引:27
|
作者
Mondal, Chanchal [1 ]
Ghosh, Debasis [2 ]
Ganguly, Mainak [1 ]
Sasmal, Anup Kumar [1 ]
Roy, Anindita [1 ]
Pal, Tarasankar [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India
[2] Indian Inst Technol, Ctr Mat Sci, Kharagpur 721302, W Bengal, India
关键词
Pseudocapacitance; Conductivity; Composite; Cyclic voltammetry; Specific capacitance; Electrode material; ELECTRODE MATERIAL; FACILE SYNTHESIS; ENERGY-STORAGE; OXIDE; COMPOSITES; CAPACITANCE; GRAPHENE; BEHAVIOR; ALPHA-CO(OH)(2); NANOSTRUCTURES;
D O I
10.1016/j.apsusc.2015.10.078
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The problem of poor electron conductivity is always associated with pseudocapacitive electrode material that deters full utilization of the active material. To have a viable solution to this problem, we report fabrication of a composite material bringing highly conductive carbon nanotube (CNT) wrapped pseudocapacitive with Co(OH)(2) nanoflakes. An in situ growth route evolves the supercapacitor via our laboratory developed modified hydrothermal reaction condition (MHT). An electrochemical investigation substantiates that the composite material electrode is highly active, which delivers a maximum specific capacitance of 603 F g(-1) (at 1 mV s(-1) scan rate), outstanding long-term cyclic stability with 96% retention at a constant current density of 1.5 A g(-1) after 1000 cycles of operation. Thus it offers almost an effortless approach to fabricate high-power and high-energy density supercapacitors. By virtue of having high-capacity of pseudocapacitive hydroxides and desirable conductivity of carbon-based materials, the as-synthesized material could be a promising candidate for the development of supercapacitor electrode material. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:500 / 507
页数:8
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