Cu(I), Ag(I) complexes containing (η5-cyclopentadienyl) [η5-1-(diphenylphosphino) cyclopentadienyl] cobaltocenium

被引：3
|
作者：
Wu, Xiang-Hua [2 ]
Guan, Jin-Tao [3 ]
Yu, Guang-Ao [1 ]
Yang, Yu-Hong [2 ]
Zhang, Bei [2 ]
Meng, Xiang-Gao [2 ]
Liu, Sheng-Hua [2 ]
机构：
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Cent China Normal Univ, Coll Chem, Key Lab Pesticide & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China
[3] Wuhan Polytech Univ, Coll Chem & Environm Engn, Wuhan 430023, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 24期
基金：
中国国家自然科学基金;
关键词：
Phosphine ligand; Cobaltocenium; Copper; Silver; Structure; CHIRAL FERROCENYL PHOSPHINES; ASYMMETRIC CATALYSIS; MOLECULAR-STRUCTURE; COUPLING REACTIONS; ANION INCLUSION; LIGANDS; 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE; SYSTEM; DERIVATIVES; BEHAVIOR;
D O I：
10.1080/00958970903215099
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
{Cu4Br5[(eta(5)-C5H4PPh2)(eta(5)-C5H5)Co](4)}[PF6](3), [(eta(5)-C5H4PPh2)(eta(5)-C5H5)Co](+) = ((eta(5)-cyclopentadienyl)[eta(5)-1-(diphenylphosphino) cyclopentadienyl] cobaltocenium) and {Ag(NO3) (CH3COCH3)[(eta(5)-C5H4PPh2)(eta(5)-C5H5)Co]}(n)[PF6](n) have been synthesized and characterized by elemental analyses, infrared spectroscopy, X-ray diffraction techniques, and by cyclic voltammetry. {Cu4Br5[(eta(5)-C5H4PPh2)(eta(5)-C5H5)Co](4)}[PF6](3) contains four coplanar copper atoms bridged by four mu-Br and one central mu(4)-Br occupying the apex of a square pyramid, and {Ag(NO3)(CH3COCH3)[(eta(5)-C5H4PPh2)(eta(5)-C5H5)Co]}(n)[PF6](n) affording a 1-D coordination zigzag polymer.
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页码：3930 / 3939
页数：10
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