Nanocomposite polymer electrolyte based on Poly(ethylene oxide) and solid super acid for lithium polymer battery

被引：91
|
作者：
Xi, JY [1 ]
Tang, XZ [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2004年 / 393卷 / 1-3期
关键词：
D O I：
10.1016/j.cplett.2004.06.054
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This Letter reports a novel PEO-based nanocomposite polymer electrolyte by using solid super acid SO42-/ZrO2 as filler. XRD, DSC, and FT-IR results prove the strong Lewis acid-base interactions between SO42-/ZrO2 and PEO chains. The addition of SO42-/ZrO2 can enhance the ionic conductivity and the lithium ion transference number of the electrolyte. The highest room temperature ionic conductivity of 2.1 x 10(-5) S cm(-1) is obtained for the sample PEO12-LiClO4-7%SO42-/ZrO2. The excellent performances such as good compatibility with lithium electrode, and broad electrochemical stability window suggest that PEO-LiClO4-SO42-/ZrO2 nanocomposite electrolyte can be used as electrolyte materials for lithium polymer batteries. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：271 / 276
页数：6
相关论文
共 50 条
  • [41] On the development of a proton conducting solid polymer electrolyte using poly(ethylene oxide)
    Patra, Sudeshna
    Puthirath, Anand B.
    Vineesh, Thazhe Veettil
    Narayanaru, Sreekanth
    Soman, Bhaskar
    Suriyakumar, Shruti
    Stephan, A. Manuel
    Narayanan, Tharangattu N.
    SUSTAINABLE ENERGY & FUELS, 2018, 2 (08): : 1870 - 1877
  • [42] Effect of fillers on magnesium-poly(ethylene oxide) solid polymer electrolyte
    Sundar, M.
    Selladurai, S.
    IONICS, 2006, 12 (4-5) : 281 - 286
  • [43] A Chitosan/Poly(ethylene oxide)-Based Hybrid Polymer Composite Electrolyte Suitable for Solid-State Lithium Metal Batteries
    Ai, Shun
    Wang, Tianyi
    Li, Tao
    Wan, Yuanxin
    Xu, Xiaoqian
    Lu, Hongyan
    Qu, Tengfei
    Luo, Shaochuan
    Jiang, Jing
    Yu, Xianghua
    Zhou, Dongshan
    Li, Liang
    CHEMISTRYSELECT, 2020, 5 (10): : 2878 - 2885
  • [44] Polymer solid electrolyte from amorphous poly[epichlorohydrin-co-(ethylene oxide)]/lithium perchlorate complex
    Kohjiya, S
    Horiuchi, T
    Miura, K
    Kitagawa, M
    Sakashita, T
    Matoba, Y
    Ikeda, Y
    POLYMER INTERNATIONAL, 2000, 49 (02) : 197 - 202
  • [45] Lithium dicyanotriazolate as a lithium salt for poly(ethylene oxide) based polymer electrolytes
    Egashira, M
    Scrosati, B
    Armand, M
    Béranger, S
    Michot, C
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (04) : A71 - A73
  • [46] Interface properties between a lithium metal electrode and a poly(ethylene oxide) based composite polymer electrolyte
    Li, Q
    Sun, HY
    Takeda, Y
    Imanishi, N
    Yang, J
    Yamamoto, O
    JOURNAL OF POWER SOURCES, 2001, 94 (02) : 201 - 205
  • [47] Analysis of Liquid, PVDF-Polymer and Polymer-Nanocomposite electrolyte for Lithium Battery
    Sathyanathan, T.
    Revathy, C.
    Sugumaran, C. Pugazhendhi
    2019 7TH INTERNATIONAL ELECTRICAL ENGINEERING CONGRESS (IEECON 2019), 2019,
  • [48] STABILITY DOMAIN OF A COMPLEXED LITHIUM SALT-POLY(ETHYLENE OXIDE) POLYMER ELECTROLYTE
    SEQUEIRA, CAC
    NORTH, JM
    HOOPER, A
    SOLID STATE IONICS, 1984, 13 (02) : 175 - 179
  • [49] COMPUTER-SIMULATION OF A POLYMER ELECTROLYTE - LITHIUM IODIDE IN AMORPHOUS POLY(ETHYLENE OXIDE)
    MULLERPLATHE, F
    VANGUNSTEREN, WF
    JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (11): : 4745 - 4756
  • [50] Electrochemical Performance of Poly(vinyl alcohol)-Based Solid Polymer Electrolyte for Lithium Polymer Batteries
    Kim, Young-Deok
    Jo, Yun-Kyung
    Jo, Nam-Ju
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2012, 12 (04) : 3529 - 3533
12345