Triphenylphosphine:: An efficient catalyst for transesterification of β-ketoesters

被引:34
|
作者
Yadav, J. S. [1 ]
Reddy, B. V. S. [1 ]
Krishna, A. D. [1 ]
Reddy, Ch. Suresh [1 ]
Narsaiah, A. V. [1 ]
机构
[1] Indian Inst Chem Technol, Div Organ Chem, Hyderabad 500007, Andhra Pradesh, India
关键词
ketoesters; triphenylphosphine; alcohol; transesterification;
D O I
10.1016/j.molcata.2006.07.060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An efficient transesterification of beta-ketoesters using triphenylphosphine (10mol%) has been described here with various alcohols. All the reactions were carryout in toluene at reflux conditions to obtained the desired products in very good yields. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:93 / 97
页数:5
相关论文
共 50 条
  • [21] Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils
    Karavalakis, Georgios
    Anastopoulos, Georgios
    Stournas, Stamos
    APPLIED ENERGY, 2011, 88 (11) : 3645 - 3650
  • [22] Transesterification of ketoesters using Amberlyst-15
    Chavan, SP
    Subbarao, YT
    Dantale, SW
    Sivappa, R
    SYNTHETIC COMMUNICATIONS, 2001, 31 (02) : 289 - 294
  • [23] TRIPHENYLPHOSPHINE HYDROBROMIDE - A MILD AND EFFICIENT CATALYST FOR TETRAHYDROPYRANYLATION OF TERTIARY ALCOHOLS
    BOLITT, V
    MIOSKOWSKI, C
    TETRAHEDRON LETTERS, 1988, 29 (36) : 4583 - 4586
  • [24] Facile transesterification of β-ketoesters under solvent-free condition using borate zirconia solid acid catalyst
    Madje, BR
    Patil, PT
    Shindalkar, SS
    Benjamin, SB
    Shingare, MS
    Dongare, MK
    CATALYSIS COMMUNICATIONS, 2004, 5 (07) : 353 - 357
  • [25] Transesterification of ketoesters with alcohols using polyaniline salts as catalysts
    Palaniappan, S
    Shekhar, RC
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2004, 15 (03) : 140 - 143
  • [26] ZnO nanoparticles: An efficient catalyst for transesterification reaction of α-keto carboxylic esters
    Soliman, Mohamed M. A.
    Karmakar, Anirban
    Alegria, Elisabete C. B. A.
    Ribeir, Ana P. C.
    Rubio, Guilherme M. D. M.
    Saraiva, Marta S.
    Guedes da Silva, M. Fatima C.
    Pombeiro, Armando J. L.
    CATALYSIS TODAY, 2020, 348 : 72 - 79
  • [27] Transesterification of β-ketoesters with alcohols catalyzed by montmorillonite K-10
    Jin, TS
    Zhang, SL
    Li, TS
    GREEN CHEMISTRY, 2002, 4 (01) : 32 - 34
  • [28] Natural clays as efficient catalyst for transesterification of β-keto esters with carbohydrate derivatives
    da Silva, FC
    Ferreira, VF
    Rianelli, RS
    Perreira, WC
    TETRAHEDRON LETTERS, 2002, 43 (07) : 1165 - 1168
  • [29] Boric acid: an efficient and environmentally benign catalyst for transesterification of ethyl acetoacetate
    Kondaiah, G. C. M.
    Reddy, L. Amarnath
    Babu, K. Srihari
    Gurav, V. M.
    Huge, K. G.
    Bandichhor, R.
    Reddy, P. Pratap
    Bhattacharya, A.
    Anand, R. Vijaya
    TETRAHEDRON LETTERS, 2008, 49 (01) : 106 - 109
  • [30] Biodiesel production by transesterification catalyzed by an efficient choline ionic liquid catalyst
    Fan, Mingming
    Huang, Jianglei
    Yang, Jing
    Zhang, Pingbo
    APPLIED ENERGY, 2013, 108 : 333 - 339