The crystal structure of copper(II) malonate trihydrate

被引：0
|
作者：
Naumov, P
Ristova, M
Soptrajanov, B
Drew, MGB
Ng, SW
机构：
[1] Sv Kiril I Metodij Univ, Fac Sci, Inst Chem, Skopje 1001, Macedonia
[2] Univ Reading, Dept Chem, Reading RG6 2AD, Berks, England
[3] Univ Malaya, Inst Postgrad Studies, Kuala Lumpur 50603, Malaysia
来源：
CROATICA CHEMICA ACTA | 2002年 / 75卷 / 03期
关键词：
crystal structure; coordination; copper; malonate; hydrogen bonding;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The compound having an empirical formula Cu8C24 H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonato-copper)-bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)(2)Cu(O2CCH2CO2)(2) . Cu(H2O)(4)](2) . [(H2O)(2)Cu(O2CCH2CO2)(2).{Cu- (H2O)(4)}(2)](2+) [(H2O)(2)Cu(O2CCH2CO2)(2)](2-). The compound crystallizes in the monoclinic P2(1)/c space group, with a 14.96(2), b = 14.97(2), c = 26.00(3) Angstrom; beta = 103.91(1)degrees; Z = 4, rho(calc) 2.064 g cm(-3).
引用
收藏
页码：701 / 711
页数：11
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