Novel solid polymer electrolytes based on poly(trimethylene carbonate) and lithium hexafluoroantimonate

被引：29
|
作者：
Manuela Silva, Maria [1 ]
Barbosa, Paula [1 ]
Evans, Alan [1 ]
Smith, Michael John [1 ]
机构：
[1] Univ Minho, Dept Quim, P-4710057 Braga, Portugal
来源：
SOLID STATE SCIENCES | 2006年 / 8卷 / 11期
关键词：
polymer electrolytes; lithium hexafluoroantimonate; conductivity; thermal stability;
D O I：
10.1016/j.solidstatesciences.2006.05.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The results of the characterization of a polymer electrolyte system based on the poly(trimethylene carbonate) host matrix, with lithium hexafluoroantimonate as guest salt, are described in this study. Electrolytes with lithium salt compositions with values of n between 5 and 100 (where n represents the total number of monomeric cation-coordinating units -O=COCH2CH2CH2O)-per lithium ion) were prepared by co-dissolution and deposition from acetonitrile. The solvent-casting technique was used to prepare flexible, transparent and self-supporting films of electrolytes which were characterized by measurements of conductivity, cyclic voltammetry, differential scanning calorimetry and thermogravimetry. (c) 2006 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：1318 / 1321
页数：4
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