Direct Internal Steam Reforming at SOFC with Anode Prepared Using NiO-SDC Composite Particles
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作者:
Kawano, M.
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Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Kansai Elect Power Co Inc, Energy Use R&D Ctr, Amagasaki, Hyogo 6610974, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Kawano, M.
[1
,2
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Matsui, T.
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Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Matsui, T.
[1
]
Kikuchi, R.
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Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Kikuchi, R.
[1
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Yoshida, H.
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Kansai Elect Power Co Inc, Energy Use R&D Ctr, Amagasaki, Hyogo 6610974, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Yoshida, H.
[2
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Inagaki, T.
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Kansai Elect Power Co Inc, Energy Use R&D Ctr, Amagasaki, Hyogo 6610974, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Inagaki, T.
[2
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Eguchi, K.
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Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, JapanKyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
Eguchi, K.
[1
]
机构:
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kansai Elect Power Co Inc, Energy Use R&D Ctr, Amagasaki, Hyogo 6610974, Japan
The dependence of anode catalytic activities on the fuel species and the operating temperatures was investigated for use in the direct internal steam-reformed power generation. The SOFCs employing Ni-SDC cermet anode fabricated from the NiO-SDC composite particles were operated in the temperature range of 700-1000 degrees C by feeding the humidified hydrogen and methane as fuels. The cell performances with humidified hydrogen fuel were higher than those with humidified methane fuel at every operation temperature. The performances at 700 and 800 degrees C were much lower than that at 1000 degrees C when the humidified methane fuel was supplied. Considering the results of the electrochemical characterization and the microstructural observation of anode, the methane conversion and the deposited carbon appeared to significantly affect the cell performances.