Synthesis, crystal and molecular structures of the novel, structurally different, cage compounds P6C4Bu(t)4SiI2 and P6C4Bu(t)4GeI2, resulting from intra-molecular coupling of two 1,2,4-triphospholyl rings

被引：15

作者：

Avent, AG ^{[1
]}

Cloke, FGN ^{[1
]}

Francis, MD ^{[1
]}

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 10期

关键词：

D O I：

10.1039/b001632m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of EI4 (E = Si or Ge) with 2 equivalents of K[P3C2Bu2t] affords the novel cage compounds P6C4Bu4t- SiI2 and (P6C4Bu4GeI2)-Ge-t respectively, whose molecular structures, determined spectroscopically and by single crystal X-ray diffraction studies, are different both in solution and in the solid state.

引用

页码：879 / 880

页数：2

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