Chemoselective hydrogen transfer reduction of unsaturated ketones to allylic alcohols with solid Zr and Hf catalysts

被引：1

作者：

De Bruyn, M ^{[1
]}

De Vos, DE ^{[1
]}

Jacobs, PA ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2002年 / 344卷 / 10期

关键词：

allylic alcohols; hafnium; heterogeneous catalysis; alpha; beta-unsaturated ketones; zirconium;

D O I：

10.1002/1615-4169(200212)344:10<1120::AID-ADSC1120>3.0.CO;2-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

alpha,beta-Unsaturated ketones were reduced to allylic alcohols with high chemo- and diastereoselectivity, using Zr and Hf compounds heterogenised on mesoporous molecular sieves.

引用

页码：1120 / 1125

页数：6

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