Chemoselective hydrogen transfer reduction of unsaturated ketones to allylic alcohols with solid Zr and Hf catalysts

被引：1
|
作者：
De Bruyn, M [1 ]
De Vos, DE [1 ]
Jacobs, PA [1 ]
机构：
[1] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2002年 / 344卷 / 10期
关键词：
allylic alcohols; hafnium; heterogeneous catalysis; alpha; beta-unsaturated ketones; zirconium;
D O I：
10.1002/1615-4169(200212)344:10<1120::AID-ADSC1120>3.0.CO;2-4
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
alpha,beta-Unsaturated ketones were reduced to allylic alcohols with high chemo- and diastereoselectivity, using Zr and Hf compounds heterogenised on mesoporous molecular sieves.
引用
收藏
页码：1120 / 1125
页数：6
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