Intercalation of tetraazamacrocycles into molybdenum disulfide

被引：32
|
作者：
Bissessur, R [1 ]
Haines, RI
Brüning, R
机构：
[1] Univ Prince Edward Isl, Dept Chem, Charlottetown, PE C1A 4P3, Canada
[2] Mt Allison Univ, Dept Phys, Sackville, NB E4L 1E6, Canada
来源：
JOURNAL OF MATERIALS CHEMISTRY | 2003年 / 13卷 / 01期
关键词：
D O I：
10.1039/b208237n
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the intercalated macrocycles are co-planar with the MoS2 sheets.
引用
收藏
页码：44 / 49
页数：6
相关论文
共 50 条
  • [21] Molybdenum disulfide nanocomposites. A new method for the intercalation of organic and organometallic species
    Benavente, E
    Gonzalez, G
    BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA, 1997, 42 (04): : 555 - 559
  • [22] Solid-state NMR study of hydrated intercalation compounds of molybdenum disulfide
    Alexiev, V
    Altenschildesche, HMZ
    Prins, R
    Weber, T
    CHEMISTRY OF MATERIALS, 1999, 11 (07) : 1742 - 1746
  • [23] Novel intercalation compound of poly[oligo(ethylene glycol)-oxalate] in molybdenum disulfide
    Bissessur, R
    Gallant, D
    Brüning, R
    JOURNAL OF MATERIALS SCIENCE LETTERS, 2003, 22 (06) : 429 - 431
  • [24] Effect of molybdenum disulfide doping with substitutional nitrogen and sulfur vacancies on lithium intercalation
    Kotsun, Alena A.
    Alekseev, Victor A.
    Stolyarova, Svetlana G.
    Makarova, Anna A.
    Grebenkina, Mariya A.
    Zubareva, Anna P.
    V. Okotrub, Alexander
    Bulusheva, Lyubov G.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2023, 947
  • [25] Lithium dynamics in molybdenum disulfide intercalation compounds studied by nuclear magnetic resonance
    Donoso, JP
    Magon, CJ
    Schneider, J
    Bloise, AC
    Benavente, E
    Sanchez, V
    Santa Ana, MA
    González, G
    BRAZILIAN JOURNAL OF PHYSICS, 2006, 36 (1A) : 55 - 60
  • [26] Structure characterization and conductive performance of polypyrrol-molybdenum disulfide intercalation materials
    Wang, TM
    Liu, WM
    Tian, J
    Shao, X
    Sun, DC
    POLYMER COMPOSITES, 2004, 25 (01) : 111 - 117
  • [27] A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
    Anyushin, A. V.
    Korotaev, E. V.
    Andreeva, A. Yu.
    Ryzhikov, M. R.
    Mainichev, D. A.
    Sokolov, M. N.
    Fedin, V. P.
    RUSSIAN CHEMICAL BULLETIN, 2016, 65 (01) : 173 - 180
  • [28] Synthesis of intercalation compounds of molybdenum disulfide with nitrogen-containing organic molecules and study of their microstructure
    Golub, AS
    Zaikovskii, VI
    Lenenko, ND
    Danot, M
    Novikov, YN
    RUSSIAN CHEMICAL BULLETIN, 2004, 53 (09) : 1914 - 1923
  • [29] Modification of molybdenum disulfide (2H-MoS2) and synthesis of its intercalation compounds
    A. S. Golub’
    D. P. Rupasov
    N. D. Lenenko
    Yu. N. Novikov
    Russian Journal of Inorganic Chemistry, 2010, 55 : 1166 - 1171
  • [30] A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide
    A. V. Anyushin
    E. V. Korotaev
    A. Yu. Andreeva
    M. R. Ryzhikov
    D. A. Mainichev
    M. N. Sokolov
    V. P. Fedin
    Russian Chemical Bulletin, 2016, 65 : 173 - 180
12345