Effect of Coordinating Solvents on the Structure of Cu(II)-4,4′-bipyridine Coordination Polymers

被引：8

作者：

Rancan, Marzio ^{[1
]}

Carlotto, Alice ^{[2
]}

Bottaro, Gregorio ^{[1
]}

Armelao, Lidia ^{[1
,2
]}

机构：

[1] Univ Padua, Dept Chem Sci, Inst Condensed Matter Chem & Technol Energy ICMAT, Natl Res Council CNR, Via Marzolo 1, I-35131 Padua, Italy

[2] Univ Padua, Dept Chem Sci, Via Marzolo 1, I-35131 Padua, Italy

来源：

INORGANICS | 2019年 / 7卷 / 08期

关键词：

coordination polymer; MOF; CP; dimensionality control; Cu(II)-4; 4 '-bipyridine; dipyridil ligand; copper; 3D; FRAMEWORK; CHEMISTRY; DESIGN; CU;

D O I：

10.3390/inorganics7080103

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvent can play a crucial role in the synthesis of coordination polymers (CPs). Here, this study reports how the coordinating solvent approach (CSA) can be used as an effective tool to control the nature of the final CP. This study exploited the system Cu(II)-4,4 '-bipyridine coupled to different coordinating solvents, such as DMA, DMF and DMSO. This allowed the isolation and structurally characterization of four new CPs: three 2D layered networks and one 1D chain. Moreover, it was evidenced that even adventitious water can play the role of the coordinating solvent in the final CP.

引用

页数：10

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