High-Pressure Viscosity Measurements for the Binary System Cyclohexane plus n-Hexadecane in the Temperature Range of (318.15 to 413.15) K

被引:17
|
作者
Rajagopal, Krishnaswamy [1 ]
Andrade, Luciana L. P. R. [1 ,2 ]
Paredes, Marcio L. L. [2 ]
机构
[1] Univ Fed Rio de Janeiro, DEQ, Escola Quim, LATCA, BR-21949900 Rio De Janeiro, Brazil
[2] Univ Estado Rio de Janeiro, PPG EQ, Inst Quim, BR-20550900 Rio De Janeiro, Brazil
来源
关键词
DENSITY; MIXTURES; LIQUIDS; MPA;
D O I
10.1021/je9000262
中图分类号
O414.1 [热力学];
学科分类号
摘要
The viscosities of binary mixtures of cyclohexane and n-hexadecane at high pressures were measured for six different compositions with an electromagnetic viscometer in the range of (6.90 to 62.05) MPa at temperatures varying from (318.15 to 413.15) K, extending the data of Tanaka et al. with a vibrating crystal viscometer and that of Wakeham and co-workers utilizing a vibrating wire viscometer, for higher temperatures. The data were correlated with the molar additive mixing rule using temperature-dependent Gaussian functions in pressure for pure component viscosities. At higher temperatures, the curvature of the viscosity-pressure function changes significantly with composition for this asymmetric mixture.
引用
收藏
页码:2967 / 2970
页数:4
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