In situ Mossbauer studies of electrochemical processes

被引：2
|
作者：
Cashion, J. D. [1 ]
Greaves, T. L. [1 ]
机构：
[1] Monash Univ, Sch Phys, Clayton, Vic 3800, Australia
来源：
HYPERFINE INTERACTIONS | 2005年 / 165卷 / 1-4期
基金：
澳大利亚研究理事会;
关键词：
Mossbauer spectroscopy; in situ electrochemistry; cyclic voltammetry; lithium-ion batteries; clay minerals; Prussian Blue;
D O I：
10.1007/s10751-006-9241-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Recent electrochemical studies involving in situ Mossbauer spectroscopy are reviewed. The principal application has been the development of new electrodes for lithium-ion batteries, where Mossbauer spectroscopy plays an important complementary role to XRD in characterizing, and usually identifying, nanocrystalline and intermediate phases of iron and tin. Other applications include the crystallography of Prussian Blue, taken using a recently developed spectrometer for acquiring multiple spectra during continuous cyclic voltammetry, valence interconversion in clay minerals and electrochemical oxygen reduction.
引用
收藏
页码：5 / 16
页数：12
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