Preparation and properties of benzotriazole functionalized alkyd-acrylic copolymer dispersions

被引：1
|
作者：
Tofangsaz, Elnaz [1 ]
Ranjbar, Niloufar [1 ]
Mahmoudi, Masoud [1 ]
Naghash, Hamid Javaherian [1 ]
机构：
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, POB 311-86145, Shahreza, Isfahan, Iran
来源：
INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 08期
关键词：
1-H-Benzotriazole; chlorodimethylsilyl benzotriazole (CDSB); methacryloxydimethylsilyl benzotriazole (MDSB); acrylic monomers; HYBRID MINIEMULSION POLYMERIZATION; GRAFTING MECHANISMS; REACTIVE DILUENTS; FILM PROPERTIES; BUTYL ACRYLATE; SYSTEMS; POLYMERS; RESIN; POLYDIMETHYLSILOXANE; MORPHOLOGY;
D O I：
10.1080/24701556.2017.1284101
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The aim of the present study was the development and characterization of a novel heterocyclic monomer bearing acrylic function with silane moieties methacryloxydimethylsilyl benzotriazole (MDSB) and its application in the preparation of alkyd-acrylic hybrid emulsions. The structural conformation of MDSB was ascertained from FT-IR and NMR spectral studies. The obtained copolymer dispersions were stable for several months and had decreased thermal stability relative to neat alkyd resin due to the lower pyrolysis temperature of acrylates. The films prepared from copolymer dispersions were all transparent. Also, the presence of MDSB affected the mechanical properties of the films.
引用
收藏
页码：1157 / 1167
页数：11
相关论文
共 50 条
  • [31] FAST METHOD OF TOTAL ACID GROUPS DETERMINATION IN FUNCTIONALIZED ACRYLIC DISPERSIONS
    UMINSKI, M
    SAIJA, LM
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 1995, 16 (06) : 511 - 519
  • [32] Preparation and properties of copolymer of graphene oxide and methyl acrylic acid and sodium methallyl sulfonate
    College of Resource and Environment, Shaanxi University of Science & Technology, Xi'an, China
    Gongneng Cailiao, 6 (06148-06152):
  • [33] LABORATORY PREPARATION AND PROPERTIES OF ALKYD RESIN FILMS
    KINSELLA, EM
    MAYNE, JEO
    JOURNAL OF THE OIL & COLOUR CHEMISTS ASSOCIATION, 1968, 51 (09): : 816 - &
  • [34] Preparation of concentrated polydisperse acrylic latex dispersions by secondary nucleation
    Brown, RFG
    Carr, C
    SURFACE COATINGS INTERNATIONAL PART B-COATINGS TRANSACTIONS, 2003, 86 (03) : 217 - 220
  • [35] PREPARATION OF URETHANE-ACRYLIC BLOCK COPOLYMER FOR ELECTROCOAT
    WOO, JTK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 6 - PMSE
  • [36] PREPARATION AND PROPERTIES OF RHEOPEXIC DISPERSIONS
    HEINE, K
    KRANZ, D
    SCHAFER, EE
    SCHWINUM, E
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1973, 29-3 : 85 - 104
  • [37] Preparation and application of an amphiphilic acrylic copolymer as a retanning agent
    Jin, Liqiang (jin-liqiang@163.com), 1600, Society of Leather Technologists and Chemists (98):
  • [38] Preparation and Application of an Amphiphilic Acrylic Copolymer as a Retanning Agent
    Jun Liqiang
    Wei Yanwei
    Wang Yulu
    Li Yanchun
    JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS AND CHEMISTS, 2014, 98 (05): : 222 - 228
  • [39] Preparation and Application of Acrylic Anionic Copolymer Modified Dispersant
    Wang X.
    Song C.
    Wan B.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2020, 36 (04): : 15 - 20and28
  • [40] Preparation and properties of new in-situ acrylic copolymer/terpolymer-clay hybrid nanocomposites
    Patel, S.
    Bandyopadhyay, A.
    Vijaybaskar, V.
    Bhowmick, Anil K.
    RUBBER CHEMISTRY AND TECHNOLOGY, 2006, 79 (05): : 820 - 834
12345