Synthesis and novel fluorescence phenomenon of terbium(III) complex with N, N′, N"-tris (2-benzimidazolmethyl) amine

被引：0
|
作者：
Yang, Tianlin [1 ]
Gao, Min [1 ]
Qin, Wenwu [2 ,3 ]
Yang, Jinhui [1 ]
机构：
[1] Ningxia Univ, Coll Chem & Chem Engn, Key Lab Energy Sources & Chem Engn, Yinchuan 750021, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China
[3] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2010年 / 49卷 / 01期
关键词：
Coordination chemistry; Fluorescence; Luminescence; Terbium; Benzimidazoles; EUROPIUM(III); LUMINESCENCE; SENSORS;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A benzimidazole ligand with a tripodal structure, N, N', N ''-tris (2-benzimidazolmethyl) an-Line, and its terbium (III) complex has been synthesized. The complex has been characterized by element analysis, IR spectra, mass spectra, thermal analysis and molar conductivity. The terbium ion is found to coordinate with the nitrogen atoms (=N-) of imidazole ring and the bridgehead nitrogen atom. The fluorescence properties of the complex in aqueous solutions have been studied. Under excitation of UV light, the complex exhibits characteristic fluorescence of terbium ion. The luminescence of terbium complex in aqueous solutions is strongly enhanced by H(+) concentration. This phenomenon makes the new complex favorable for use in fluorescence switches and sensors. The mechanism of the fluorescence enhancement by protonation of the nitrogen atoms (-NH-) of imidazole ring is due to the suppressed photoinduced electron transfer fluorescence quenching on addition of acid.
引用
收藏
页码：45 / 48
页数：4
相关论文
共 50 条
  • [21] Heteroleptic chromium(III) tris(diimine) [Cr(N∧N)2(N′∧N′)]3+ complexes
    Schoenle, Jonas
    Constable, Edwin C.
    Housecroft, Catherine E.
    Neuburger, Markus
    Zampese, Jennifer A.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 51 : 75 - 77
  • [22] Tris(thiocyanato-kappa N)tris(triphenylphosphine oxide-kappa O)terbium(III)
    Pham, Lam N.
    Thames, Anthony T.
    White, Frankie D.
    Xiang, Kang Rui
    Sykora, Richard E.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1531 - +
  • [23] REACTION OF COMPLEX IONS OF TRIS-N-2-HYDROXYETHYLETHYLENE DIAMINE-COBALT(III) AND TRIS-N-2-OXYPROPYLETHYLENEDIAMINE-COBALT(III)WITH SODIUM TETRAPHENYLBORATE
    KARPEISKAYA, EI
    KUKUSHKI.YN
    TROFIMOV, VA
    ZHURNAL NEORGANICHESKOI KHIMII, 1972, 17 (05): : 1484 - +
  • [24] Synthesis and Crystal Structure of Tris-(N–N dimethyl benzylammonium)-hexachlorobismuthate(III)
    Salwa Nasri
    Fatma Zouari
    Hafed El Feki
    Journal of Chemical Crystallography, 2008, 38 : 729 - 732
  • [25] Determination of Trace Terbium(III) with N, N, N′-Tri(3-indolemethanal)triaminotriethylamine Based on a New Fluorescence Enhancement System
    Tianlin Yang
    Xishi Tai
    Wenwu Qin
    Weisheng Liu
    Minyu Tan
    Analytical Sciences, 2004, 20 : 357 - 361
  • [26] Determination of trace terbium(III) with N,N′,N"-tri(3-indolemethanal)triaminotriethylamine based on a new fluorescence enhancement system
    Yang, TL
    Tai, XS
    Qin, WW
    Liu, WS
    Tan, MY
    ANALYTICAL SCIENCES, 2004, 20 (02) : 357 - 361
  • [27] Synthesis and structure of N,N'N''-tris(2-hydroxyethyl)-N,N,N',N',N'',N''-hexamethyl-2,2',2''-nitrilotris(ethylammonium) trichloride
    Koh, TS
    Fallon, GD
    Baklien, A
    Hearn, MTW
    Jackson, WR
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1996, 49 (06) : 723 - 725
  • [28] (2-methylpropane-1,2 diamine-κ2 N,N′)-[tris(2-aminoethyl)amine-κ4 N,N′,N′′,N′′′]-nickel(II) dipercholorate
    Lin, YC
    Lu, TH
    Li, CY
    Liao, FL
    Chung, CS
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1398 - M1400
  • [29] Crystal structure and thermal decomposition of tris(nitrato)di(N,N,N,N-tetrabutyl malonamide) complex of Pr(III)
    Cui, Y
    Sun, GX
    Li, YX
    Zhang, ZW
    Sun, SX
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (11) : 1723 - 1726
  • [30] (TRIS[N-(SALICYLIDENE)-2-AMINOETHYL]AMINE)COBALT(III) ACETONITRILE HEMIHYDRATE
    ELERMAN, Y
    KABAK, M
    SVOBODA, I
    GESELLE, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 1694 - 1696
12345