Synthesis and structure of a trinuclear rhenium cluster complex [PEt3H][Re-3(mu(3)-S)(mu-S)(3)Cl-6(PEt3)(3)]

被引:9
|
作者
Miyake, N [1 ]
Imoto, H [1 ]
Saito, T [1 ]
机构
[1] UNIV TOKYO, SCH SCI, DEPT CHEM, TOKYO 113, JAPAN
关键词
D O I
10.1246/cl.1997.913
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of [Re-3(mu(3)-S)mu-S-2)(3)Cl-6]Cl with triethylphosphine in benzene formed [PEt3H][Re-3(mu(3)-S)mu-S)(3)Cl-6(PEt3)(3)]. The triangular cluster has eight metal cluster electrons and the cluster core resembles that of [Mo-3(mu(3)-S)(mu-S)(3)Cl4L5] cluster complexes.
引用
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页码:913 / 914
页数:2
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