Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

被引：13

作者：

Jaeger, M ^{[1
]}

Stumpf, R ^{[1
]}

Troll, C ^{[1
]}

Fischer, H ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, D-78457 Constance, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 11期

关键词：

D O I：

10.1039/b002228o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)-carbene] complexes of molybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form novel chelated hepta-coordinated Fischer-type tricarbonyl-(bishalogeno)carbene molybdenum(II) and tungsten(II) complexes.

引用

页码：931 / 932

页数：2

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