Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

被引：13
|
作者：
Jaeger, M [1 ]
Stumpf, R [1 ]
Troll, C [1 ]
Fischer, H [1 ]
机构：
[1] Univ Konstanz, Fachbereich Chem, D-78457 Constance, Germany
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 11期
关键词：
D O I：
10.1039/b002228o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)-carbene] complexes of molybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form novel chelated hepta-coordinated Fischer-type tricarbonyl-(bishalogeno)carbene molybdenum(II) and tungsten(II) complexes.
引用
收藏
页码：931 / 932
页数：2
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