Aryl sulfoxides via palladium-catalyzed arylation of sulfenate anions

被引：94
|
作者：
Maitro, Guillaume [1 ]
Vogel, Sophie [1 ]
Prestat, Guillaume [1 ]
Madec, David [1 ]
Poli, Giovanni [1 ]
机构：
[1] Univ Paris 06, Chim Organ Lab, UMR 7611, CNRS,Inst Chim Mol FR 2769, F-75252 Paris 05, France
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 26期
关键词：
D O I：
10.1021/ol062315a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium- catalyzed arylation of sulfenate anions generated from,- sulfinyl esters can take place under biphasic conditions. This hitherto unknown reaction provides a simple, mild, and efficient route to aryl sulfoxides in good yields. The development of a new pseudo- domino type I procedure involving a sulfinylation followed by a Mirozoki - Heck coupling is also described.
引用
收藏
页码：5951 / 5954
页数：4
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