Tl2S-Sb2S3-Bi2S3 quasi-ternary system

被引：1

作者：

Dzhafarov, Ya. I. ^{[1
]}

Babanly, M. B. ^{[1
]}

机构：

[1] Baku State Univ, Baku, Azerbaijan

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 11期

关键词：

TL4BI2S5;

D O I：

10.1134/S0036023609110254

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Tl2S-Sb2S3-Bi2S3 quasi-ternary system (system A) was studied using DTA, X- ray powder diffraction, microstructure examination, and microhardness measurements. TlSbS2-Tl4Bi2S5(TlBiS2, Bi2S3), Sb2S3-TlBiS2, Tl3SbS3-TlBiS2(Bi2S3), and [TlSb0.5Bi0.5S2]-Tl2S isopleths; isothermal sections at 500 K; and liquidus surface projection of system A were constructed. Characteristic features of the title system are extensive fields of solid solutions extended along the TlSbS2-TlBiS2 quasi-binary section and a continuous solubility belt 1-2 mol % wide extended along the Sb2S3-Bi2S3 binary subsystem. Primary separation fields of phases and the types and coordinates of invariant and monovariant equilibria in system A were determined.

引用

页码：1839 / 1843

页数：5

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