Kinetic studies of solvent and pressure effects on the thermal isomerization of palladium dithizonate

被引：0
|
作者：
Sueishi, Y [1 ]
Matsumoto, K [1 ]
机构：
[1] Okayama Univ, Fac Sci, Dept Chem, Okayama 7008530, Japan
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2000年 / 16卷 / 02期
关键词：
metal dithizonate; kinetic study; solvent effect; pressure effect;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The isomerization of mercury bisdithizonate having tetrahedral stereochemistry occurs in each ligand independently and is unaffected by the presence of the second ligand attached to the same central metal. The effects of solvent and pressure on the thermal isomerization of the square-planar Pd dithizonate complex were studied to determine the influence of ligand on the isomerization rate. The results were compared to those obtained with Hg(HDz)2. The mechanistic implications for the thermal isomerization of Pd(HDz)2 were presented.
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页码：141 / 145
页数：5
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