Bis(μ-2,2′-bipyridin-6-olato)-κ3 N, N′: O;κ3 O: N′,N′-dicopper(I, II) dichlorocuprate(II)

被引：5
|
作者：
Guo, Hong-Xu [1 ]
Rao, Zhi-Ming [1 ]
Wang, Qing-Hua [1 ]
机构：
[1] Zhangzhou Normal Univ, Dept Chem & Environm Sci, Fujian 363000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536806050720
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C10H7N2O)(2)][CuCl2], is formulated as containing a mixed-oxidation-state [Cu-2(obpy)(2)](+) cation (Hobpy is 2,2'-bipyridin-6-ol) and a [CuCl2](-) anion, both of which lie on inversion centres. The mixed-valence Cu-I,Cu-II is coordinated by one O and two N atoms of two obpy ligands. The Cu center dot center dot center dot Cu interaction [2.3805 (9) angstrom] results in a square-planar environment for the Cu-I,Cu-II atoms. The Cu-II atom in the anion is coordinated by two chloride ions in a linear geometry.
引用
收藏
页码：M637 / M638
页数：2
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